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Author Topic:   New helium retention work suggests young earth and accelerated decay
Tranquility Base
Inactive Member


Message 31 of 122 (21378)
11-02-2002 4:10 PM
Reply to: Message 25 by Brad McFall
11-02-2002 1:00 PM


Brad
Somehow I knew you'd be reading Wolfram. I wonder when the paperback version will come out?

This message is a reply to:
 Message 25 by Brad McFall, posted 11-02-2002 1:00 PM Brad McFall has not replied

  
Tranquility Base
Inactive Member


Message 32 of 122 (21379)
11-02-2002 4:11 PM
Reply to: Message 22 by edge
11-02-2002 9:25 AM


Edge
I'll get back to you on that.

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 Message 22 by edge, posted 11-02-2002 9:25 AM edge has not replied

  
Tranquility Base
Inactive Member


Message 33 of 122 (21622)
11-05-2002 7:57 PM


Nos
In the other thread http://EvC Forum: How about teaching evolution at Sunday school? -->EvC Forum: How about teaching evolution at Sunday school?
I said
quote:
The recent helium work shows that the physical process of diffusion constrains the age of rocks in an almost as clear way as radiodecay.
Radiodecay had to be understood by science first. After 100 years of that we went back and looked at the consequences that simple diffusion has on the issue.
The you said:
quote:
It was found that carbon dating is only accurate up to 50,000 years, this is why they now use different methods to find the age of things.
So what does that have to do with it? I suspect you are not up to scratch on these issues. Mechanical diffusion of nuclear decay generated helium is an indpendent way of trying to date rocks. This helium is generated during the uranium decay series. i.e. the billions of years half-life series used to date the planet.
[This message has been edited by Tranquility Base, 11-05-2002]

Replies to this message:
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edge
Member (Idle past 1725 days)
Posts: 4696
From: Colorado, USA
Joined: 01-09-2002


Message 34 of 122 (21641)
11-06-2002 12:17 AM
Reply to: Message 33 by Tranquility Base
11-05-2002 7:57 PM


quote:
Originally posted by Tranquility Base:
The you said:
quote:
It was found that carbon dating is only accurate up to 50,000 years, this is why they now use different methods to find the age of things.
So what does that have to do with it? I suspect you are not up to scratch on these issues. Mechanical diffusion of nuclear decay generated helium is an indpendent way of trying to date rocks.
No, it is a way of showing that [He] is not a very good clock.
Humphreys appears to believe this and yet says that the same clock requires a young earth. Does this make sense to you?

This message is a reply to:
 Message 33 by Tranquility Base, posted 11-05-2002 7:57 PM Tranquility Base has not replied

Replies to this message:
 Message 35 by TrueCreation, posted 11-06-2002 4:45 PM edge has replied

  
TrueCreation
Inactive Member


Message 35 of 122 (21722)
11-06-2002 4:45 PM
Reply to: Message 34 by edge
11-06-2002 12:17 AM


"No, it is a way of showing that [He] is not a very good clock."
--I wouldn't expect dating by He diffusion to be a reliable 'clock', though it could serve as a relative dating method. Tranquility and the RATE team seems to make the claim that the analysis is not cooperative with such 'Ga' scale ages given by isotopic measurements. Of course this is my assertion made without considering what the data actually does say about He diffusion.
------------------

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 Message 34 by edge, posted 11-06-2002 12:17 AM edge has replied

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edge
Member (Idle past 1725 days)
Posts: 4696
From: Colorado, USA
Joined: 01-09-2002


Message 36 of 122 (21753)
11-07-2002 12:18 AM
Reply to: Message 35 by TrueCreation
11-06-2002 4:45 PM


quote:
Originally posted by TrueCreation:
e: "No, it is a way of showing that [He] is not a very good clock."
--I wouldn't expect dating by He diffusion to be a reliable 'clock', though it could serve as a relative dating method.
So that fact that helium can diffuse out of zircon crystals does not bother you in using this method as a clock? After all of the discussions regarding argon loss and retention you are going back on the creationist position that these make radiodating undependable?
quote:
Tranquility and the RATE team seems to make the claim that the analysis is not cooperative with such 'Ga' scale ages given by isotopic measurements.
Please follow the logic of my previous posts and tell me how a 6000 year old (according to Humphreys) zircon looks any different in He content than a 6 trillion year old zircon.
quote:
Of course this is my assertion made without considering what the data actually does say about He diffusion.
Actually, it is irrelevant. Humphreys' data does not tell him what he thinks it does.

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wehappyfew
Inactive Member


Message 37 of 122 (21823)
11-07-2002 10:39 PM
Reply to: Message 1 by Tranquility Base
11-01-2002 1:08 AM


[QUOTE]Originally posted by Tranquility Base:
[B]In all the kafuffle and misunderstandings between our Joe Meert and ICR's Russell Humphreys et al we have not been able to celebrate an important creationist result!
Acts and Facts Magazine | The Institute for Creation Research
On the face of it, it appears that the radioactively generated helium present in zircons suggests that the helium was generated only in the last 4,000 to 14,000 years rather than gradually over the last 1.5 billion years. There is simply too much of it (up to 58% compared to the long-age expected 0.0002%) still in the rocks. The diffusion rates are experimentally measured and, on the face of it, rule out the ancient ages. [/quote]
[/b]
Dos the RATE book contain these "experimentally measured" diffusion rates?
quote:
Here we can discuss how this finding fits into the creation model.

OK. Sounds like fun. I've been doing some research on the subject (obviously I need it after starting the whole -196C closure confusion).
If you have the numbers from those diffusion experiments, we can use them to mathematically evaluate the Creation model WRT helium diffusion in zircons, etc. We can also compare them to the diffusion parameters measured by Reiners (the ones that Humphreys claims support his results)...
http://www.geology.yale.edu/~reiners/zirconpaper040401.pdf
If you would, please, consider the Arrhenius plots in Figure 2 and the data in Table 1 of Reiners. From them we can infer diffusion rates relevant to the Jimez zircons, and plug them into the equilibrium age equation (incorrectly labeled closure interval in eq 22 from Preprint of section 10) that Humphreys uses.
I would like to see if you come up with the same results I did.
I find it very interesting that Humphreys calculates a temperature of -196C (77K) for his "retention temperature". How can he do this? If you look at how the Arrhenius plots work, this requires extrapolating experimental data along the X-axis measured in the 12 to 18 range (the units are 10000/temp) up to 130 (10000/77 = 130). Does this seem reasonable?
Did you notice that Humphreys calulates a closure temp for the Jimez zircons using standard geological assumptions? I wonder what the closure temp would be if we assumed a 4-14K age for the Earth and the extremely fast cooling rates implied by that. And what about the unspoken assumption in conventional science of unchanging radiodecay constants? If we use the decay acceleration required by the YEC timeframe, and plug that into Humphrey's definition of closure temp...
"... a temperature at which the rates of loss and production are equal. That point is essentially what Dodson meant by the closure temperature."
... then we need to adjust our calculated closure temp upwards until we find a diffusion rate that is proportionally higher. Are you willing to give it a try, TB?

This message is a reply to:
 Message 1 by Tranquility Base, posted 11-01-2002 1:08 AM Tranquility Base has replied

Replies to this message:
 Message 38 by Tranquility Base, posted 11-08-2002 5:56 PM wehappyfew has not replied

  
Tranquility Base
Inactive Member


Message 38 of 122 (21911)
11-08-2002 5:56 PM
Reply to: Message 37 by wehappyfew
11-07-2002 10:39 PM


Wehappy
The RATE book contains the extrapolated helium diffusion constant from the argon experimental one:
Extrap He: 10^-15 to 10^-17 cm^2/s (temp dependent)
Expt Ar: 10^-19 to 10-22 cm^2/s (temp dependent)
The experimental He diffusion (EDIT from fusion!) rate was mentioned to be in agreement with the extrapolated one last year:
The Institute for Creation Research
and represents a rapid diffusion coeffeicen about 5-orders of magnitude greater than what the long-age model needs. If He diffused at the Ar rate things would be all hunky-dory for you.
I have it on good authority that the data will be presented at a creation conference and be up on the web some time in 2003.
[This message has been edited by Tranquility Base, 11-08-2002]

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Replies to this message:
 Message 39 by edge, posted 11-08-2002 7:39 PM Tranquility Base has replied

  
edge
Member (Idle past 1725 days)
Posts: 4696
From: Colorado, USA
Joined: 01-09-2002


Message 39 of 122 (21930)
11-08-2002 7:39 PM
Reply to: Message 38 by Tranquility Base
11-08-2002 5:56 PM


quote:
Originally posted by Tranquility Base:
The RATE book contains the extrapolated helium diffusion constant from the argon experimental one:
Extrap He: 10^-15 to 10^-17 cm^2/s (temp dependent)
Expt Ar: 10^-19 to 10-22 cm^2/s (temp dependent)
Of course the diffusion rates are temperature dependent. Now what temperatures are we talking about?
quote:
The experimental He fusion rate was mentioned to be in agreement with the extrapolated one last year:
The Institute for Creation Research
What do you mean 'fusion rate,' and what experimental rate are you talking about? You have given us an 'extrapolated' rate and then say that the experimental rate compares well with the 'extrapolated' rate from last year. Then explain how the experimental value was determined, and how that relates to natural conditions of the zircons.
quote:
...and represents a rapid diffusion coeffeicen about 5-orders of magnitude greater than what the long-age model needs. If He diffused at the Ar rate things would be all hunky-dory for you.
Please explain why such rates are a problem for us. I your own words, please. You have seen Humphreys' own data that shows an equilibrium [He] for the zircons in question. No matter what the diffusion rate, Humphreys says that the He concentration will always be the equilibrium value after the 'closure interval.' So, what does this have to do with diffusion and the age of the crystals?
quote:
I have it on good authority that the data will be presented at a creation conference and be up on the web some time in 2003.
I can't wait.

This message is a reply to:
 Message 38 by Tranquility Base, posted 11-08-2002 5:56 PM Tranquility Base has replied

Replies to this message:
 Message 40 by Tranquility Base, posted 11-08-2002 7:44 PM edge has replied

  
Tranquility Base
Inactive Member


Message 40 of 122 (21931)
11-08-2002 7:44 PM
Reply to: Message 39 by edge
11-08-2002 7:39 PM


^ Being a nuclear physicist at heart I sub-conciously substituted He fusion for He diffusion!
Temp: between 130C and 280C.
The argon exp data is published: Grove M & Harrison TM American Minerologist 81, 940-951 (1996). The extrapolaitons are mainstream, what anyone would expect (helium is a lot smaller) and the He diff is now experimental too.
I don't claim that I completely understand what Humphrey's is going on about on his website but I haven't spent time on it either. I suspect that you shouldn't assume that he doesn't know what he is talking about.
[This message has been edited by Tranquility Base, 11-08-2002]

This message is a reply to:
 Message 39 by edge, posted 11-08-2002 7:39 PM edge has replied

Replies to this message:
 Message 41 by edge, posted 11-08-2002 9:33 PM Tranquility Base has not replied

  
edge
Member (Idle past 1725 days)
Posts: 4696
From: Colorado, USA
Joined: 01-09-2002


Message 41 of 122 (21940)
11-08-2002 9:33 PM
Reply to: Message 40 by Tranquility Base
11-08-2002 7:44 PM


quote:
Originally posted by Tranquility Base:
The argon exp data is published: Grove M & Harrison TM American Minerologist 81, 940-951 (1996). The extrapolaitons are mainstream, what anyone would expect (helium is a lot smaller) and the He diff is now experimental too.
I don't claim that I completely understand what Humphrey's is going on about on his website but I haven't spent time on it either. I suspect that you shouldn't assume that he doesn't know what he is talking about.
Well, since he tells us that there is too much He in zircons and then shows us why there can be only so much He in zircon, I think it's a good bet that he does not know what he's talking about. The fact that he invented the 'closure interval' to cover up his other errors is also evidence. Not to mention his magnetic reversal fiasco.
All Humphreys has shown (if he is right) is that there should be a sill value of He concentration in zircons, and that He diffusion MIGHT occur at a faster rate than previously thought. Any other conclusions are only the wishful thinking of a die-hard creationist attempting to bend the facts to fit a preconceived idea.
You still have not made the case that this is a 'problem for evolution,' either. So, He diffuses faster than previously thought. Where does it diffuse to? Even Humphreys admits that some He stays in the zircon. Why is it too much? This whole argument makes no sense at all. Perhaps that is why you do not fully understand what Humphreys is saying.

This message is a reply to:
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wehappyfew
Inactive Member


Message 42 of 122 (21948)
11-08-2002 11:36 PM


Thanks for looking that up for us, TB.
Now... sorry to be a bother, but we really must be quite careful with terms and numbers here. What you gave us is not enough. As edge pointed out, a diffusivity value is relevant only at a specified temperature. A range of 130-280C is sufficient to make diffusivity vary by a factor of about a MILLION. So when you quote 10^-15 to 10^-17 cm^2/s, is that for 130degC or 280degC ???
Please clarify what you mean by "extrapolated helium diffusion constant from the argon experimental one." Are you saying the helium diffusion number is extrapolated from [i][b]argon[/i][/b] diffusion values??? That makes no sense. You must have meant something else. Please help us poor confused skeptics.
And when you said this...
quote:
If He diffused at the Ar rate things would be all hunky-dory for you.
Did you realize that you are comparing apples to oranges? Argon diffusion is usually measured in K-feldspar or biotite - never zircon. Zircon contans no potassium, therefore no argon to diffuse out.
When you get the values and temps straight, would you be willing to go through the calculations with me, TB?
But just as an amusing side-note in the mean time...
...if we take your numbers at face value... i.e. the diffusivity at 280degC = 10^-15 cm^2/s, and diffusivity at 130degC = 10^-17 cm^2/s...
...then use those numbers to calculate the Ea (activation energy) and Do...
...then use that to calculate closure temperature, then we arrive at the value Tc = 77K, which, in Celsius is...
...you guessed it... exactly minus 196 degrees C !!!
Of course I am not claiming that Humphreys actually did this. Its just an amusing coincidence, right?
Right???

Replies to this message:
 Message 43 by Tranquility Base, posted 11-09-2002 12:03 AM wehappyfew has not replied

  
Tranquility Base
Inactive Member


Message 43 of 122 (21949)
11-09-2002 12:03 AM
Reply to: Message 42 by wehappyfew
11-08-2002 11:36 PM


In the RATE book, the extrapolated He diffusion constants in biotite are (as measured from Fig 7-7, p348):
10^-15 cm^2/s @ 280 C
10^-17 cm^2/s @ 160 C
Neither the experimental argon nor extrapolated helium change by 6 orders of magnitude over that temperature range.

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Replies to this message:
 Message 44 by edge, posted 11-09-2002 10:23 AM Tranquility Base has not replied

  
edge
Member (Idle past 1725 days)
Posts: 4696
From: Colorado, USA
Joined: 01-09-2002


Message 44 of 122 (21972)
11-09-2002 10:23 AM
Reply to: Message 43 by Tranquility Base
11-09-2002 12:03 AM


quote:
Originally posted by Tranquility Base:
In the RATE book, the extrapolated He diffusion constants in biotite are (as measured from Fig 7-7, p348):
10^-15 cm^2/s @ 280 C
10^-17 cm^2/s @ 160 C
Neither the experimental argon nor extrapolated helium change by 6 orders of magnitude over that temperature range.

Since we are now talking about biotite, what are the He rates (experimental and extrapolated) in biotite? I thought you also had experimental He diffusion rates, too. So how much do they vary?
Also, you keep talking about 'extrapolated' data. Just how far is this data extrapolated? And where do the data come from? Are we talking the same kind of extrapolation that we see in the c-decay stories where they include 19th century measurements in the data set?
TB, please remember that the RATE book is not the Third Testament. You have no real commitment to it. If you truly have a PhD and are truly interested in science, it is your duty to crtitcally analyze what this book says. For some reason, I think have not taken the time to do this.

This message is a reply to:
 Message 43 by Tranquility Base, posted 11-09-2002 12:03 AM Tranquility Base has not replied

  
wehappyfew
Inactive Member


Message 45 of 122 (21987)
11-09-2002 12:28 PM


Thanks TB,
Diffusion in biotite is, of course, nearly irrelevant to this discussion, as Humphreys hinted in the Impact 352 article. I was hoping it had the zircon data in it, too.
Anyway, with the correct temps and diffusivity, we can now calculate Tc for [b][i]biotite[/b][/i], just for practice. I get about 30 to 40 degC. How about you?
Like edge, I am also worried about that word "extrapolated". Did you mean to say that? I thought RATE had experimental data?
Finally, you said:
"Neither the experimental argon nor extrapolated helium change by 6 orders of magnitude over that temperature range."
Correct. But now you have switched to biotite, not zircon as I was originally discussing, and you changed 130 to 160degC. According to the experimentally measured diffusivity for zircon from Reiners(2002), the difference between 280 and 160degC would be about 20,000 times - for zircon.
From ICR Impact352:
quote:
So the RATE project commissioned experiments to measure helium diffusion in zircon and biotite samples specifically from the Fenton Hill borehole...
...Our experiments showed that we need to account for both diffusion from zircon and biotite, but zircon is more important.
This certainly seems to imply that zircon data is already published in the RATE book.
From the recent AIG spin piece:
quote:
...as the new RATE experiments (confirmed by new published data from other laboratories) show, helium diffuses so rapidly out of zircon that it should have all but disappeared after about 100,000 years.
So what are Humphreys' "experimentally" derived diffusivity constants for zircon? Do they really agree with Reiners(2002)? If they do, then we can just use what Reiners has already published on the web:
http://www.geology.yale.edu/~reiners/zirconpaper040401.pdf
What do you think, TB, would you like to apply Humphreys' calculations to Reiners' data?
*note to edge: Humphreys' Tci equation is not made-up. He copied it from Wolf(1998) or independently derived it in a similar fashion. Either way, he should have given credit for it to Wolf (who called it the equilibrium age), and he uses it wrong (no surprise there, heh?).*

Replies to this message:
 Message 46 by edge, posted 11-09-2002 1:01 PM wehappyfew has replied

  
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