I see your reasoning, sir, yet you do not see mine. You are concluding that knowing what is 'right' and what is 'wrong' is required in order to sin. It is not. Sin is disobedience to God. Period. Ignorance is not a defence.
God told Adam and, it is implied, Eve not to eat of the fruit. Truth be told, it is irrelevant who told her, as the decree ultimately came from God. Whether she knew the reason why, is also irrelevant. Wether she could or could not comprehend that going against God would be 'wrong,' is irrelevant. She clearly states her 'knowledge' that God told her 'no.' She chose to ignore that command. She disobeyed God, and, ergo, sinned.
Cause and effect, sir, is very simple and exists beyond a shadow of a doubt. I will admit that they did not, perhaps, know true sin until after eating the fruit. However, it does not change the fact that they defied a clear order from God. There can be no excuse for doing the exact opposite of an order. They cannot claim ignorance, they were told.
Her decision was, indeed, an informed one. She knew the outcome of her decision, she knew the source of the command, she knew the command. I fail to see how this is an uninformed decision? Knowing all pertinent facts, she chose.
Ignoring all this, your statements seem to indicate a belief that Adam and Eve were simpletons, with only a partly functioning brain, largely incapable of making decisions. They were not. They were perfect beings, unlike ourselves. But, again, that would be a discussion for another day.
The point is, sir, she did not accept God's word. She did not accept His Command. She accepted the word of another. That is sin. Her knowledge of wether or not it was sin is moot. She sinned, followed shortly there after by her husband.